In order to achieve targeted release of corrosion inhibitors，and solve the situation of further corrosion of oil and gas pipeline metals，a rapidly responding container was synthesized by modified Stober method. Organic silicon nanoparticles （S-SNPs）embedded with different imines were synthesized by changing the mole ratio of inorganic and organic silicon sources and loaded with MBT to obtain the intelligent corrosion inhibitor MBT@S-SNPs，and its intelligent anticorrosion performance was studied. The results showed that S-SNPs was stable in a neutral environment，but would degrade in an acidic environment，which could achieve a controlled release of corrosion inhibitor. In addition，the impedance of the corrosion sample containing MBT@S-SNPs could be 5 times than that of the blank sample，which effectively alleviated the occurrence of corrosion. The response degradation of S-SNPs and its interaction with corrosion inhibitors resulted in a high load（16%）and pH response release of corrosion inhibitors. The S-SNPs could respond to pH changes caused by corrosion and had broad application prospects in the targeted repair of corrosion.