高含凝析油气井泡沫排液用起泡剂研究
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Research of Foam Frother for High Content of Condensate Oil-Gas Well
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    摘要:

    针对高含凝析油气井泡沫排液困难,以长链烷基二甲基叔胺为主要原料、双氧水为氧化剂,合成了一种长链烷基氧化胺OA,引入少量与其有协同增效作用的磺酸盐类表面活性剂,形成抗凝析油起泡剂主剂ZJ。再与多种稳定泡沫物质复配,得到一种高抗凝析油的复配起泡剂,配方为:2% ZJ+0.04% NaOH+0.03%瓜尔胶。ZJ在高凝析油条件下(50%~70%)的泡沫排液性能明显优于常用起泡剂UT-11c。70℃下,凝析油含量为70%时,ZJ的起泡能力(初始泡沫高度)为13.7 cm,泡沫稳定性(3 min后的泡沫高度)为9.8 cm,携液能力为12 mL/15 min。复配后的起泡能力为15.4 cm,泡沫稳定性为11.8 cm,携液能力为60 mL/15 min。抗温可达90℃,抗盐可达8%。在川渝地区五宝场凝析气藏两口高含凝析油(大于50%)积液气井中成功运用,使两口间歇生产井恢复了连续生产,产气量提高约40%。

    Abstract:

    According to the foam drainage difficulty for condensate oil-gas well, a kind of long chain alkyl amine oxide OA was synthesized using a long chain alkyl dimethyl tertiary amines as the main raw material and hydrogen peroxide as oxidant. Anticoagulant condensate oil frother main agent ZJ was obtained which introduced a small amount sulfonic acid salts surfactant with synergistic effect. It was compounded with stable foam agent to form a high anticoagulant compound foaming agent. The formula was obtained as follows: 2% ZJ, 0.04% NaOH, 0.03% guar gum. Under the condition of high condensate oil (50%—70%), the foam drainage performance of ZJ was superior to that of common foaming agent UT-11c. When the content of condensate oil was 70% at 70℃, the foaming capacity (initial foam height) of ZJ was 13.7 cm, foam stability (foam height after 3 min) was 9.8 cm, and liquid carrying capacity was 12 mL/15 min. The three data changed to 15.4 cm, 17.8 cm and 60 mL/15 min respectively after compounding. The resistance temperature was 90℃, and salt resisting mass fraction was 8%. This compound foaming agent was successfully applied in two effusion wells with high content of condensate oil (above 50%) of gas condensate in Wubaochang possession. Two intermittent production wells returned to continuous production, and the gas production increased about 40%.

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陈雅溪,王 尧,李小可,陈大钧,熊 颖.高含凝析油气井泡沫排液用起泡剂研究[J].油田化学,2013,30(4):544-547.
CHEN Ya-xi, WANG Yao, LI Xiao-Ke, CHEN Da-Jun, XIONG Ying. Research of Foam Frother for High Content of Condensate Oil-Gas Well[J]. OILFIELD CHEMISTRY,2013,30(4):544-547.

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  • 在线发布日期: 2014-01-17
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