耐温耐盐交联聚合物颗粒的制备与评价
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十三五国家科技重大专项“表层风化壳黏弹调流体系的制备与评价”(项目编号34400007-17-ZC0607-0130)


Preparation and Performance Evaluation of Crosslinked Polymer Particle with Temperature Resistance and Salt Tolerance
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    摘要:

    常规的丙烯酰胺交联聚合物的耐温耐盐性较差,在高温高矿化度的地层条件下会硬化,导致变形性较差,无法对深部地层产生调剖。针对以上问题,向体系中引入耐温功能单体N-乙烯基吡咯烷酮(NVP)和N,N-二甲基丙烯酰胺(DMAA),以二乙烯苯为交联剂、甲醛合次硫酸氢钠和过硫酸铵为引发剂、钠土为稳定剂,制得耐温耐盐的共聚物颗粒,通过向体系中引入钠土增强聚合物的韧性与刚度,研究了单体配比、各物质加量对交联聚合物吸水膨胀倍数和储能模量的影响。结果表明,交联聚合物适宜的合成条件为:单体质量分数 30%,NVP 与DMAA摩尔比6∶4,二乙烯苯加量0.25%,甲醛合次硫酸氢钠和过硫酸铵加量各0.15%,钠土加量3%。通过特制粉碎设备,经过两级造粒,实现颗粒粒径在1~10 mm可调。在130℃、矿化度为22×104 mg/L的条件下高温静置90 d,交联聚合物颗粒仍处于吸水膨胀状态,储能模量约5000 Pa,交联聚合物的耐温耐盐性提高。

    Abstract:

    Conventional acrylamide crosslinked polymer had poor temperature and salt resistance,and would harden under high temperature and high salinity formation conditions,resulting in poor deformation and failure of profile control in deep formation. In order to solve these problems,the temperature and salt tolerant copolymer particle was prepared by introducing the functional monomers N-vinyl pyrrolidone(NVP)and N,N-dimethyl acrylamide(DMAA)into the system,using diethylene benzene as crosslinking agent,formaldehyde sodium bisulfate and ammonium persulfate as initiator and sodium soil as stabilizer. By introducing clay into the system to enhance the toughness and stiffness of polymer,the effects of monomer ratio,addition of various substances on water absorption expansion multiple and energy storage modulus of crosslinked polymer were studied. The results showed that the suitable synthesis condition of the crosslinked polymer was obtained as follows:30% monomer mass fraction,6∶4 NVP and DMAA molar ratio,0.25% diethylene benzene dosage,0.15% formaldehyde sodium bisulfate,0.15% ammonium persulfate dosage,3% sodium soil mass fraction. Through special crushing equipment and two-stage granulation,the particle size could be adjusted from 1 to 10 mm. Under the condition of 130℃ and salinity of 22×104 mg/L,the crosslinked polymer particle was still in the state of water absorption and expansion,and the energy storage modulus was about 5000 Pa after standing for 90 days. The temperature and salt tolerance of the crosslinked polymer was improved.

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宋龙飞,葛际江,吴 昊,蒋 平.耐温耐盐交联聚合物颗粒的制备与评价[J].油田化学,2019,36(3):415-421.
SONG Longfei, GE Jijiang, WU Hao, JIANG Ping. Preparation and Performance Evaluation of Crosslinked Polymer Particle with Temperature Resistance and Salt Tolerance[J]. OILFIELD CHEMISTRY,2019,36(3):415-421.

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  • 在线发布日期: 2019-10-11
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