耐盐耐高温三元聚合物压裂液稠化剂的制备与性能评价
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Preparation and Performance Evaluation of Terpolymer Thickening Agent with Salt Tolerance and High Temperature Resistance for Oilfield Fracturing Fluid
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    摘要:

    为获得在超高矿化度及210℃高温条件下使用的压裂液稠化剂,以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)和丙烯酰吗啉(ACMO)为原料制备了三元聚合物稠化剂(APC-30),考察了APC-30 的增黏性、耐温耐盐性和稳定性;研究了APC-30 与有机锆交联剂BPA混合交联后形成的冻胶压裂液的耐温耐剪切性、黏弹性和破胶性能。结果表明,在单体质量比AM/AMPS/ACMO=70∶24∶6、复合引发剂K2S2O7-NaHSO3加量0.4%、抑制剂HCOONa加量1.2%的条件下制备的APC-30 的增黏性、耐温耐盐性及稳定性均优于二元聚合物压裂液稠化剂AP-30。在矿化度450 g/L、温度200℃、剪切速率170 s-1的条件下,APC-30 的黏度保留率为35%。具有六元杂环结构的吗啉基团的引入可明显提高压裂液冻胶的耐温抗剪切能力。APC-30 压裂液冻胶在210℃、170 s-1下剪切2 h 的黏度为175.8 mPa·s。APC-30 压裂液冻胶具有高弹低黏的特性和优异的压裂悬砂能力,破胶液残渣含量低、易返排,可用于油田现场压裂施工。图9表4 参24

    Abstract:

    In order to obtain the thickening agent used in fracturing fluid on the condition of ultra-high salinity and 210℃ high temperature,a terpolymer thickening agent APC-30 was prepared by acrylamide(AM),2-acrylamido-2-methylpropanesulfonic acid(AMPS)and acryloyl morpholine(ACMO). The viscosifying performance,salt-tolerance and thermal stability of APC-30 were investigated. Furthermore,the temperature and shear resistance,viscoelasticity and breaking property of the gel fracturing fluid with the combination of APC-30 and organic zirconium crosslinking agent BPA were studied. The results showed that APC-30 which synthesized on the condition of 70∶24∶6 monomer mass ratio of AM/AMPS/ACMO,0.4% composite initiator K2S2O7-NaHSO3 and 1.2% chain transfer agent HCOONa presented a better viscosifying performance,thermal stability and salt resistance than binary polymer thickening agent AP-30. The viscosity retention of APC-30 was 35% under the condition of 450 g/L salinity,200℃ temperature and 170 s-1 shear rate. The introduction of morpholine group with six-membered heterocyclic structure could obviously improve the temperature and shear resistance of fracturing fluid gel. The viscosity of APC-30 fracturing fluid gel was 175.8 mPa·s after shearing at 210℃ and 170 s-1 for 2 hrs. The APC-30 fracturing fluid gel had the characteristics of high elasticity,low viscosity as well as excellent sand carrying capacity. The broken liquid of fracturing fluid had low residue content and easily backflow. The new type fracturing fluid could be used for fracturing operation on site.

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薛俊杰,朱卓岩,欧阳坚,王超,王源源,王凤,陈国浩,刘强.耐盐耐高温三元聚合物压裂液稠化剂的制备与性能评价[J].油田化学,2018,35(1):41-46.
XUE Junjie, ZHU Zhuoyan, OUYANG Jian, WANG Chao, WANG Yuanyuan, WANG Feng, CHEN Guohao, LIU Qiang. Preparation and Performance Evaluation of Terpolymer Thickening Agent with Salt Tolerance and High Temperature Resistance for Oilfield Fracturing Fluid[J]. OILFIELD CHEMISTRY,2018,35(1):41-46.

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  • 在线发布日期: 2018-04-26
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